According to Wikipedia LEL / UEL for petrol is 1.4% / 7.6% with stoichiometry at 6.9% which you rightly say is around the proportion 14:1.
And Hydrogen LEL / UEL is 4% / 75% - wasn't quite so far out with that one.
Acetylene LEL / UEL is 2.5% / 82% so I was also wrong about Hydrogen being the most dangerous since acetylene has wider explosive limits - the problem with acetylene cylinders in fires is that pressure can build up in the cylinder and if it gets to around 30psi it's likely to explode with extreme violence - to keep the gas pressure below this it is dissolved in a liquid - usually acetone within the cylinder - an acetylene cylinder which has been transported on it's side should be left upright for 24 hours before use to allow to re-dissolve so the gas is at it's normal pressure.